Because you like Monty Burns in The Simpsons
Chef is a swinging bachelor and former R&B singer with a leopard-skin upholstered couch and some great stories. See them in South Park.
James Gordon happens to be the one guy in Gotham City with proper morals who doesn't also run around in a cape. See them in DC Extended Universe.
Michaelangelo is an above-ground crime-fighter by night, and a pizza-eating, sewer-dwelling mutant ninja turtle by day. See them in Teenage Mutant Ninja Turtles.
A suave manipulator, Sebastian Valmont is valiantly fighting off a developing conscience. See them in Cruel Intentions.
Emma Frost's superpower: transforming her body into an unbreakable diamond. See them in X-Men Series.
Samantha Jones is a try-sexual who'll try anything once. See them in Sex and the City.
This lab mouse has one thing on his huge brain: trying to take over the world on a nightly basis. See them in Pinky and the Brain.
Born and raised in the darkness, Bane is determined to have the city totally under his control so that he can demolish it. See them in DC Extended Universe.
A monstrous pirate captain, Davy Jones is quite literally heartless. See them in Pirates of the Caribbean: the Curse of the Black Pearl.
Angela Martin is uptight and puritanical, outside of the affair she's having with a co-worker. See them in The Office.