Because you like Yotsuba Koiwai in Yotsuba&!
Years of being the less desirable Vargas sibling have given Romano quite an inferiority complex, as well as the temper to match. See them in Axis Powers Hetalia.
The witty Aku would be an ideal dinner guest, if he weren't a demon. See them in Samurai Jack.
While his twin tries to save lives, Millions Knives does the best to end them. See them in Trigun.
What Mako Mankanshoku lacks in common sense, she makes up for in sheer optimism and force of personality. See them in Kill la Kill.
Years of brutal winters, foreign invasions, and crippling loneliness have left Russia's mental state far from wholly intact. See them in Axis Powers Hetalia.
Misaki Nakahara is keeping tabs on her newest project: recluse Tatsuhiro Sato. See them in Welcome to the NHK.
For Celty Sturluson, it's rather upsetting to be the only headless girl in a city filled with full-bodied humans. See them in Durarara!!.
Shana is a red-haired warrior with a black-and-white worldview. See them in Shakugan no Shana.
Oscar Jarjayes is a sword-swinging, fearless Commander of the Royal Guard who cross-dresses as a man. See them in Rose of Versailles.
Gou Matsuoka offers to help as manager of a swim team, believing that they're the only ones who can help her brother. See them in Free! Iwatobi Swim Club.
Firo Prochainezo is swept up in a world of mysterious women, alchemists, and rumors of a wine that makes it drinkers immortal. See them in Baccano!.
Konata Izumi has a live-now, worry-later view of the world. See them in Lucky Star.