Because you like Rue in Princess Tutu
After several hundred years of shutting himself out from the rest of the world, Japan's not used to dealing with nations, See them in Axis Powers Hetalia.
After Rintarou Okabe develops the Phone Microwave, some of his fantasies start to seem uncomfortably real. See them in Steins;Gate.
England may cultivate the image of a well-bred gentleman, but he has both the temper and mouth of a seasoned sailor. See them in Axis Powers Hetalia.
Ichigo Momomiya is a bubbly student by day, magical cat-powered superhero by night. See them in Tokyo Mew Mew.
If there's power in being average, Mikado Ryugamine will find it and use it. See them in Durarara!!.
There are rumors that the Spirit was an Egyptian Pharaoh in his past, but without any memories, he doesn't know how true they are. See them in Yu-Gi-Oh! .
Undercover as an average high school student, Kallen Stadtfeld is actually most at ease when the action's fast, furious, and dangerous. See them in Code Geass.
Years of brutal winters, foreign invasions, and crippling loneliness have left Russia's mental state far from wholly intact. See them in Axis Powers Hetalia.
Given his ability to wrench street signs from the ground, Shizuo Heiwajima is a useful one to have in dangerous Ikekuburo. See them in Durarara!!.
After alien Haruko rides in on her Vespa, giant robots spouting from Naota Nandaba's forehead soon become the least of his worries. See them in FLCL.
Yuri is living in the afterlife, which takes the form of a high school where no one dies. But if you follow the school's rules and live a "normal" life you vanish. See them in Angel Beats!.
The personification of America is all about superheroes, hamburgers, and spreading democracy and justice. See them in Axis Powers Hetalia.