Because you like Gloria Delgado-Pritchett in Modern Family
After Rintarou Okabe develops the Phone Microwave, some of his fantasies start to seem uncomfortably real. See them in Steins;Gate.
Years of being the less desirable Vargas sibling have given Romano quite an inferiority complex, as well as the temper to match. See them in Axis Powers Hetalia.
Sephiroth wants nothing more than to seize the power of the Lifestream in order to become a god. See them in Final Fantasy Series.
For the sake of science, Kurisu Makise will persevere no matter how deep into the dark secrets of the world she finds herself. See them in Steins;Gate.
The personification of America is all about superheroes, hamburgers, and spreading democracy and justice. See them in Axis Powers Hetalia.
After several hundred years of shutting himself out from the rest of the world, Japan's not used to dealing with nations, See them in Axis Powers Hetalia.
Years of brutal winters, foreign invasions, and crippling loneliness have left Russia's mental state far from wholly intact. See them in Axis Powers Hetalia.
A crabby troll, Karkat Vantas is perpetually angry about his lot in life. See them in Homestuck.
If it means fulfilling her ambitions, Satsuki Kiryuin will show neither shame nor hesitation. See them in Kill la Kill.
The cutest kitty this side of the galaxy, Nepeta Leijon is mischievous, caring, and obsessed with romance. See them in Homestuck.
England may cultivate the image of a well-bred gentleman, but he has both the temper and mouth of a seasoned sailor. See them in Axis Powers Hetalia.
Given his ability to wrench street signs from the ground, Shizuo Heiwajima is a useful one to have in dangerous Ikekuburo. See them in Durarara!!.