Because you like Black Star in Soul Eater
For Celty Sturluson, it's rather upsetting to be the only headless girl in a city filled with full-bodied humans. See them in Durarara!!.
China has five thousand years of history, and he's optimistic he'll win over the Allied Powers to the wisdom of his ways. See them in Axis Powers Hetalia.
Undercover as an average high school student, Kallen Stadtfeld is actually most at ease when the action's fast, furious, and dangerous. See them in Code Geass.
Yuri is living in the afterlife, which takes the form of a high school where no one dies. But if you follow the school's rules and live a "normal" life you vanish. See them in Angel Beats!.
Kagami Hiiragi keeps her grades up, helps at Takanomiya Shrine, serves as class president, and hangs out with her friends. See them in Lucky Star.
What Mako Mankanshoku lacks in common sense, she makes up for in sheer optimism and force of personality. See them in Kill la Kill.
With his perfectly combed hair and flashy military outfits, France can charm the pants off of anyone—well except his fellow nations, it seems. See them in Axis Powers Hetalia.
Suzaku Kururugi defeats enemies with his flashy but deadly jump kicks. But he's willing to sacrifice himself for peace. See them in Code Geass.
An alien, a time-traveler, and an esper are following Haruhi Suzumiya, who – unknown to herself – is a near-omnipotent reality warper. See them in The Melancholy of Haruhi Suzumiya.
The last war left his economy devastated, and now Germany is engaged in another war and stuck with two barely trained allies for help. See them in Axis Powers Hetalia.
With most of the people that Sango loved now gone, the only thing she wants is to kill the demon who destroyed her village. See them in Inuyasha.
If it means fulfilling her ambitions, Satsuki Kiryuin will show neither shame nor hesitation. See them in Kill la Kill.