Because you like Harry Tasker in True Lies
His murderous megalomania aside, Loki is quite charming. Just don't mention his strapping older brother; he's a tad jealous. See them in Marvel Cinematic Universe.
With great power comes great responsibility, but Peter Parker always seems to get the short end of that bargain. See them in Marvel Cinematic Universe.
Belle has ready every storybook in town, and she's slowly realizing that life is no fairytale. See them in Beauty and the Beast.
A dreamy space cadet, Luna Lovegood has never met a conspiracy theory she didn't believe in. See them in Harry Potter Series.
Smart and sensitive Sam Winchester tried to escape the family business, but ghosts have a way of haunting you. See them in Supernatural.
A wildly brilliant detective, Sherlock Holmes can figure out everything except how to interact with other human beings. See them in Sherlock.
He's an eccentric pirate making it up as he goes along. He's Jack Sparrow, savvy? See them in Pirates of the Caribbean: the Curse of the Black Pearl.