Because you like Anna Kone in PEN15
Insightful about everyone else's neuroses, Rose Lalonde is not as aware of her own. See them in Homestuck.
A crabby troll, Karkat Vantas is perpetually angry about his lot in life. See them in Homestuck.
Kathryn Merteuil may be a vain sociopath, but you won't be able to look away. See them in Cruel Intentions.
Irene Adler has to use both her brains and her body to survive. Luckily, she's usually the most brilliant person in the room. See them in Sherlock.
Cinderella will sacrifice herself to keep her family's memory alive. See them in Cinderella (Live Action).
Barbara Kean is loving, selfless, and caring. But, she's less stable than she'd like to admit. See them in Gotham.
Sally Albright is high maintenance who she thinks she's low maintenance. But she's still worth it. See them in When Harry Met Sally....
The singer and ukulele player of her girl band, Sugar "Kane" Kowalczyk is the life of a party and the woman of a man's dreams. See them in Some Like It Hot.
Whether it's randomly bursting into song or writing Nancy Drew fan-fiction, Jess proudly marches to the beat of her own drum. See them in New Girl.
Bucky Barnes used to be a good-hearted American soldier. Now he's the cold-hearted Winter Soldier. See them in Marvel Cinematic Universe.
This barber doesn't cut hair. Sweeney Todd sends his clients down a chute to be baked into his partner-in-crime's pies. See them in Sweeney Todd: The Demon Barber of Fleet Street.
A few millennia in the mortal realm have caused DEATH to be quite enamored of life. See them in Discworld.