Because you like Yvaine in Stardust
For the sake of science, Kurisu Makise will persevere no matter how deep into the dark secrets of the world she finds herself. See them in Steins;Gate.
After several hundred years of shutting himself out from the rest of the world, Japan's not used to dealing with nations, See them in Axis Powers Hetalia.
Years of brutal winters, foreign invasions, and crippling loneliness have left Russia's mental state far from wholly intact. See them in Axis Powers Hetalia.
If it means fulfilling her ambitions, Satsuki Kiryuin will show neither shame nor hesitation. See them in Kill la Kill.
Insightful about everyone else's neuroses, Rose Lalonde is not as aware of her own. See them in Homestuck.
Gou Matsuoka offers to help as manager of a swim team, believing that they're the only ones who can help her brother. See them in Free! Iwatobi Swim Club.
A deadbeat dad and small-time con-artist, Frank Gallagher gives nothing and yet expects everything. See them in Shameless.
An ironic hipster with a healthy dose of self-deprecation, Dave strives to be cool at all costs. See them in Homestuck.
A crabby troll, Karkat Vantas is perpetually angry about his lot in life. See them in Homestuck.