Because you like John Constantine in Constantine
Jade Jade Harley might not be the best at reading social cues, but her bravery and selflessness means she's a great friend to have. See them in Homestuck.
Chris Chambers is from a family of social outcasts and criminals, and he wants more than anything to avoid ending up like them. See them in Stand By Me.
GLaDOS will supply the food when you get together: a delicious cake. Of course, it could just be a trap so she can kill you. It’s hard to say. See them in Portal Series.
Bob Parr is an ex-superhero now focused on being a dad, but he misses the action. See them in The Incredibles.
Riley Blue is trying to outrun her bad luck, but she might not be fast enough. See them in Sense8.
With an abundant supply of alcohol, nice restaurants, and free will, Crowley is a demon who is thoroughly enjoying his time on Earth. See them in Good Omens: The Nice and Accurate Prophecies of Agnes Nutter, Witch.
Javert is an inspector with a single-minded focus: to bring criminals to justice. See them in Les Miserables.
Clarice Starling is patiently working with one serial killer to stop another. See them in The Silence of the Lambs.
As Jane Villanueva grapples with a truly unexpected pregnancy, she realizes that her life is "now the stuff of telenovelas." See them in Jane the Virgin.
Rory Williams is a caring companion whose specialty is looking after others. See them in Doctor Who.