Because you like Eliza Doolittle in My Fair Lady
Severus Snape is a misanthropic potions teacher with a vindictive streak. See them in Harry Potter Series.
Castiel might be an immortal angel, but the human world is still more than a little confusing. See them in Supernatural.
It's hard to tell if Dean Winchester cares more about saving the world or his 1967 Chevy Impala. See them in Supernatural.
What Ron Weasley lacks in motivation and book smarts, he makes up for in loyalty and street smarts. See them in Harry Potter Series.
An escaped convict on a mission, Sirius Black is brooding, brave, and reckless. See them in Harry Potter Series.
L is enigmatic, child-like, and one of the smartest people in the world. See them in Death Note.
His murderous megalomania aside, Loki is quite charming. Just don't mention his strapping older brother; he's a tad jealous. See them in Marvel Cinematic Universe.
A daring conman, Flynn Rider is so charismatic that you might not mind when he steals from you. See them in Tangled.
After surviving consecutive fights-to-the-death (damn you, President Snow!), Katniss Everdeen is thrust to the front lines of a real war. See them in The Hunger Games .